First, notice the terms "maraging
steels" (pural) and "these materials" in their
reference. Maraging steel is not a single alloy as many people
seem to believe, but is actually a description of a group of
different, yet related, steel alloys that possess a similar chemical
makeup and range of higher-strength mechanical properties.
In fact, most golfers have not even been
using the proper pronunciation of this sophisticated classification
of steel alloys. The correct pronunciation of this family of
high-strength steels is mar-AGE'-ing, not "MARRIAGE-ing"
nor "MAR'-ange-ing".
A maraging steel is a steel alloy with
a very low percentage of carbon which can form an iron-nickel
martensite crystalline structure that can be age-hardened
to achieve greater strength, hardness and toughness. Hence the
term mar-AGE-ing.
To Golfers, maraging is a term that many
are using to reference a single metal; to metallurgists, maraging
is simply a description of certain high nickel, high cobalt or
chromium content steel alloys that can be specifically heat treated
to achieve very high strengths.
When most metals are formed into a product,
whether by forging, casting or any other fabrication method,
the product can be subjected to a variety of heating and cooling
processes which can significantly change their strength, hardness
or other mechanical properties. Whatever the heating and cooling
methods, these process known as heat treatment
are a vital part of the manufacture of most metal parts.
For example, most golfers are familiar
with the alloy used to make steel metal and iron heads known
as and labeled as 17-4ph. The numbers 17 and 4 refer to the percentage
of chromium (15-17.5%) and nickel (3-5%) percent of the steel,
but the letters 'ph' refer to the manner in which the steel is
heat treated after it is formed into the shape of the head. The
'ph' in the alloy designation stands for precipitive hardening,
which means the 17-4 heads are heated to a specific temperature
after which they are quench cooled through immersion in water
or special composition of oil.
This heating and rapid reduction in temperature
allows the 17-4 steel to achieve both the higher level of strength
and hardness desired by the foundry. In addition, process creates
a specific and advantageous orientation of molecules in the 17-4
alloy to prevent the metal from becoming more brittle than desired.
After conventional heat treatment, the
maraging steel is very strong, and hard, but it is very brittle.
To restore toughness, the maraging steel is heated again and
held at a lower temperature for a period, after which it is slowly
cooled. This process slightly reduces the strength and hardness,
but more than makes up for it by restoring ductility (ability
to stretch) which increases toughness and makes the metal more
able to withstand impact with the ball. Because this process
of secondary heating and cooling takes a longer time than liquid
immersion process, the term used to describe this is aging.
From the standpoint of the metal, there
are several types of steel that can be classified as maraging
steel in their chemistry. The change in the alloy makeup is dramatic;
which range in tensile strength from just under 200.000 psi all
the way up to nearly 400,000 psi. It is this change in the steel's
chemistry - largely an increase in the nickel and molybdenum
along with an increase in the chromium content - that allows
maraging steels to be fabricated and processed to be harder and
stronger than the traditional steel used for clubhead manufacture
such as 17-4 or 431.
But hardness and strength alone are not
the key properties which could potentially enhance the performance
of clubhead. ONLY IF THE MARAGING STEEL IS ENGINEERED PROPERLY
in the clubhead design can it produce a positive improvement
in shot making from the standpoint of slight distance increase
and a significant change in the impact feel.
The words "engineered properly"
are far more important than the words harder and stronger when
it comes to using a maraging steel in the manufacture of a clubhead.
Golfers cannot be trapped into believing that all clubheads made
with a maraging steel in the face are going to be magic clubs.
They are not! In fact, it does not really matter if a maraging
steel alloy is used to fabricate the clubface; it is only important
that the strength and other significant mechanical properties
are high enough and matched properly with the design of the striking
face.
Regardless as to whether the clubface metal
is maraging steel or 17-4ph stainless, if it is matched correctly
to the right face thickness and secured properly to the body
of the clubhead, the materials can make for better golf clubhead
design. In reality, the steel used to fabricate the face of the
Orlimar Tri-Metal is a high-strength steel alloy manufactured
by the Custom Steel Corporation, USA called Custom 465. Custom
465 contains a significant percentage of titanium which is incorporated
in the alloy to boost its strength so that a thinner face construction
can used without fear of fracture. The tensile strength of the
Custom 465 is well within the range exhibited by maraging steel;
In fact, it is much higher than most of the maraging steel used
in the manufacture of clubheads today, but it still is not maraging
steel in mind of a metallurgist.
The face thickness of a metal clubhead
must be designed with both the strength of the clubhead metal
and the impact stresses placed on the clubface kept in the forefront
of the designer's mind.
It is an established fact that the predominant
alloy used in the manufacture of steel metal woods is called
17-4ph stainless steel. But the most popular steel used in the
production of investment cast iron is called 431 stainless steel.
So what the difference?
The answer is chemistry. The chief difference
between 17-4ph stainless steel and 431 stainless steel is that
17-4ph steel contains an average 15 to 17.5 chromium and 3.5
to 5 percent of nickel along with a high percentage of iron and
other trace elements. In contrast, 431 steel contains on an average
15 to 17 percent of chromium and 1.25 to 2.5 percent of nickel
with its remaining complement of iron and other trace of elements.
Those seemingly subtle differences allow
for the 17-4ph steel to be on the average some 20 percent higher
in strength than 431 steel. As a result, a club designer knows
that the face of 10-degree-lofted driver made from 17-4ph steel
will need to be at least 3mm thick in order to withstand impacts
from the golfers with swing speeds to up to 140mph. Accordingly,
designers also know that if a driver were made from 431 steel,
the lower strength of that alloy requires the clubface to be
made at least 4mm thick to stand up to the same stress. Obviously,
designers reject 431 steel for metal woods because with a face
thickness of 4 mm, the maximum size that 431 steel driver could
be and still not exceed the normal driver head weight would be
165cc, which would be far smaller than the majority of golfers
would buy.
Typically, maraging steel can be sourced
which demonstrate strengths from 200,000 psi up to 4000,000 psi.
The range in strength between the various alloys of maraging
steels is determine by the percentage of the various elements
in the steel as well as in the manner in which the steel are
processed, or heat treated, after they are formed into the shape
of the clubface.
So the trick is not in the metal, its hardness,
its strength or its elastic modulus. Instead the secret lies
in how that metal and its specific hardness and strength and
elasticity is actually utilized within a particular clubhead
design.
Philip Ang,
1999-2000 Winner International Clubmaker of the Year
conferred by Golf Clubmakers Association (GCA) - USA compiles this article from Golfsmith Tech
Report.